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Thermodynamics cannot predict corrosion rates.

Corrosion reaction equation. The value of n of course depends primarily on the nature of the metal. The green coating is mainly Copper II Carbonate CuCO3 caused by slow chemical reactions involving the copper metal and water and carbon dioxide. The chemical formula of rust is Fe 2 O 3nH 2 O The process of rust formation is due to a series of chemical reactions.

2 Cu H2O CO2 O2 Cu OH2 CuCO3. Corrosion of metal is a redox reaction as the metal loses electrons to oxygen and water which act as the oxidising agents to receive the electrons. In many natural environments the cathodic reaction is either the reduction of protons.

Reactions may be considered electrochemical in nature. Corrosion engineering is the field dedicated to controlling and preventing corrosion. Rust consists of hydrated iron III oxides Fe2O3.

The equation for this reaction is. The Fe2 ions produced in the initial reaction are then oxidized by atmospheric oxygen to produce the insoluble hydrated oxide containing Fe3 as represented in the following equation. Thus almost every case of aqueous corrosion can be reduced to these equations either singly or in combination.

Galvanic corrosion also called bimetallic corrosion or dissimilar metal corrosion is an electrochemical process in which one metal corrodes preferentially when it is in electrical contact with another in the presence of an electrolyteA similar galvanic reaction is exploited in primary cells to generate a useful electrical voltage to power portable devices. Consider the corrosion of zinc by water or moist air. According to the electrochemical model for iron corrosion the corrosion process takes place via two separate half-reactions.

Rusting is the common term for corrosion of iron and its alloys such as steel. COPPER CORROSION The green coating on copper metal called a Patina. This process is a reduction-oxidation reaction in which the metal is being oxidized by its surroundings often the oxygen in air.

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